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However, Pitt's off-screen escapades should have come as no surprise to Aniston. In the past he's been involved with his Kalifornia co-star Juliette Lewis, Claire Forlani (Meet Joe Black) and former fiance Gwyneth Paltrow (his co-star in Seven). C.'s Tate Donovan may not be an A-list actor, but he has managed to date two of Hollywood's hottest leading ladies. top Vince Vaughn and Aniston have been snapped cuddling up to each other on the set of The Break Up, despite denials that they are an item.

In the past, the Wedding Crashers star has been linked with actresses Ashley Judd, Joey Lauren Adams (Big Daddy), Janeane Garofalo and Drea de Matteo (The Sopranos).

The two have signed on to star in The Loop, a love story revolving around the romance between a highway patrolman and a librarian.

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Counting Crow's lead singer Adam Duritz can brag that he dated two-thirds of the female stars of Friends.

Duritz dated Jennifer Aniston briefly and was an item for two years with Courteney Cox.

Urban recently split with supermodel Nikki Taylor, while Kidman's most recent romances include billionaire Stephen Bing, rocker Lenny Kravitz and of course, couch jumper Tom Cruise.

top Tom Cruise's love affair with Katie Holmes became old news when the whole Brad-Jen-Angelina triangle surfaced.

It is her first marriage despite serious relationships with director Quentin Tarantino and Olivier Martinez. It seems like only yesterday that the pop princess was dating Justin Timberlake, having a fling with Colin Farrell and was getting her marriage to childhood friend Jason Alexander annulled.

top Marc Anthony and wifey Jennifer Lopez appear to be settling into marriage (his second, her third).

top If men can do it so can women -- marry younger people, that is.

Oscar winner Mira Sorvino, 37, married waiter/aspiring actor Christopher Backus, 23, last year. top Britney Spears and hubby Kevin Federline are awaiting the arrival of their baby boy any day now.

Recently there have been rumors that he and actress Mary-Louise Parker are an item after turning up at the Golden Globes awards together, but the two claim they are just old friends. Looks, money, successful careers and what appeared to be a happy marriage.

Depending who you're voting for (Aniston or Jolie) the split came in light of rumors that Pitt and Angelina Jolie were getting a little too chummy on the set of Mr. Smith or that Aniston wanted to focus more on her career than starting a family. He dated Aniston from 1995 to 1998 and even appeared as Rachel's love interest Joshua, on several episodes of Friends.

Sandra Bullock recently tied the knot with Discovery Channel's Monster Garage star Jesse James in a down home country wedding.

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